MCDHF and RCI calculations of energy levels, lifetimes and transition rates for 3l3l′, 3l4l′, and 3s5l states in Ca IX – As XXII and Kr XXV
نویسندگان
چکیده
Multiconfiguration Dirac-Hartree-Fock (MCDHF) calculations and relativistic configuration interaction (RCI) calculations were performed for states of the 3l3l′, 3l4l′ and 3s5l configurations in the Mg-like ions Ca IX – As XXII and Kr XXV. Valence and core-valence electron correlation effects are accounted for through large configuration state function expansions. Calculated excitation energies are in very good agreement with observations for the lowest levels. For higher lying levels observations are often missing and present energies aid line identification in spectra. Lifetimes and transition data are given for all ions. There is an excellent agreement for both lifetimes and transition data with recent multiconfiguration Hartree-Fock Breit Pauli calculations.
منابع مشابه
Combining Multiconfiguration and Perturbation Methods: Perturbative Estimates of Core–Core Electron Correlation Contributions to Excitation Energies in Mg-Like Iron
Large configuration interaction (CI) calculations can be performed if part of the interaction is treated perturbatively. To evaluate the combined CI and perturbative method, we compute excitation energies for the 3l3l′, 3l4l′ and 3s5l states in Mg-like iron. Starting from a CI calculation including valence and core–valence correlation effects, it is found that the perturbative inclusion of core...
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